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Zirconium
Electrons per shell 2,8,18,10,2
Electron Configuration [Kr] 4d2 5s2 open electron config
Ground state 3F2
Atomic Volume 14.1 cm3 mol-1
Electronegativity 1.33
Magnetic ordering No data
Mass magnetic susceptibility 1.66 x 10-8
Molar magnetic susceptibility 1.514 x 10-9
Speed of sound 3800 m s-1
Thermal Properties
Enthalpy of Atomization 598 kJ mol-1 @25°C
Enthalpy of Fusion 23 kJ mol-1
Enthalpy of Vaporisation 566.7 kJ mol-1
Heat Capacity 25.36 J mol-1 K-1
Thermal Conductivity 22.6 W m-1 K-1
Thermal Expansion 5.7 μm m-1 K-1
Hardness
Brinell hardness 650 MPa
Mohs hardness 5.0
Vickers hardness 903 MPa
Elastic Properties
Poisson ratio 0.34
Shear modulus 33 GPa
Young's modulus 68 GPa
Electrical Properties
Electrical resistivity 4.2 x 10-7 Ω m
Electrical conductivity 0.0236 106/cm Ω
Chemical Properties
Electrochemical Equivalent 0.8509 g Ah-1
Electron Work Function 4.05 eV
Valence Electron Potential (-eV) 80
Ionization Potential  
First 6.84
Second 13.13
Third 22.99
Incompatibilities Potassium nitrate (KNO3), oxidizers.
Flammability
Combustible
Energy Levels
Kα1 (intensity 100) 15.7751 KeV
Kα2 (intensity 50) 15.6909 KeV
Kβ1 (intensity 16.6) 17.6678 KeV
Kβ2 (intensity 3.2) 17.9663 KeV
Kβ3 (intensity 7.9) 17.6501 KeV
Lα1 (intensity 100) 2.04236 KeV
Lα2 (intensity 10) 2.0399 KeV
Lβ1 (intensity 44) 2.1244 KeV
Lβ2 (intensity 1.8) 2.2194 KeV
Lβ3 (intensity 4) 2.2014 KeV
Lβ4 (intensity 1.5) 2.1878 KeV
Lγ1 (intensity 0.5) 2.3027 KeV
Lγ3 (intensity 3) 1.876 KeV
Ll (intensity 6) 1.7906 KeV
Atomic Radii
Empirical 155 pm
Bohr Radius 206 pm
Covalent Radius 148 pm
Van der Waals No data.
Triple covalent 121 pm
Metallic 160 pm
Oxidation States
Main Zr+4
Other Zr0, Zr+1, Zr+2, Zr+3
Ionisation Energies (kJ mol-1) show graph
M - M+ 660
M+ - M2+ 1267
M2+ - M3+ 2218
M3+ - M4+ 3313
M4+ - M5+ 7860
M5+ - M6+ 9500
M6+ - M7+ 11200
M7+ - M8+ 13800
M8+ - M9+ 15700
M9+ - M10+ 17500
Vapour Pressure
P (Pa) 1 10 100 1K 10K 100K
T (K) 2639 2891 3197 3575 4053 4678
Crystal Structure
Structure Hexagonal close packed
a = 323.2 pm
b = 323.2 pm
c = 514.7 pm
α = 90°
β = 90°
γ = 120°